|
Wrought iron is an iron alloy with a very low carbon (less than 0.08%) content in contrast to cast iron (2.1% to 4%), and has fibrous inclusions known as slag up to 2% by weight. It is a semi-fused mass of iron with slag inclusions which gives it a "grain" resembling wood, that is visible when it is etched or bent to the point of failure. Wrought iron is tough, malleable, ductile, corrosion-resistant and easily welded. Before the development of effective methods of steelmaking and the availability of large quantities of steel, wrought iron was the most common form of malleable iron. A modest amount of wrought iron was used as a raw material for refining into steel, which was used mainly to produce swords, cutlery, chisels, axes and other edged tools as well as springs and files. The demand for wrought iron reached its peak in the 1860s with the adaptation of ironclad warships and railways. However, as properties such as brittleness of mild steel improved, it became less costly and more widely available than wrought iron, whose usage then declined. Many items, before they came to be made of mild steel, were produced from wrought iron, including rivets, nails, wire, chains, rails, railway couplings, water and steam pipes, nuts, bolts, horseshoes, handrails, wagon tires, straps for timber roof trusses, and ornamental ironwork. Wrought iron is no longer produced on a commercial scale. Many products described as wrought iron, such as guard rails, garden furniture and gates, are actually made of mild steel.〔 They retain that description because in the past they were wrought (worked) by hand.〔Daniel, Todd (May 3, 1997), Clearing the Confusion Over Wrought Iron, http://www.artmetal.com/project/NOMMA/WROUGHT.HTM, retrieved 2008-01-05〕 ==Terminology== The word "wrought" is an archaic past participle of the verb "to work," and so "wrought iron" literally means "worked iron". Wrought iron is a general term for the commodity, but is also used more specifically for finished iron goods, as manufactured by a blacksmith. It was used in that narrower sense in British Customs records, such manufactured iron was subject to a higher rate of duty than what might be called "unwrought" iron. Cast iron, unlike wrought iron, is brittle and cannot be worked either hot or cold. Cast iron can break if struck with a hammer. In the 17th, 18th and 19th centuries, wrought iron went by a wide variety of terms according to its form, origin, or quality. While the bloomery process produced wrought iron directly from ore, cast iron or pig iron were the starting materials used in the finery forge and puddling furnace. Pig iron and cast iron have higher carbon content than wrought iron, but have a lower melting point than iron or steel. Cast and especially pig iron have excess slag which must be at least partially removed to produce quality wrought iron. At foundries it was common to blend scrap wrought iron with cast iron to improve the physical properties of castings. For several years after the introduction of Bessemer and open hearth steel, there were different opinions as to what differentiated iron from steel; some believed it was the chemical composition and others that it was whether the iron heated sufficiently to melt and "fuse". Fusion eventually became generally accepted as relatively more important than composition below a given low carbon concentration.〔Thomas J. Misa. ''A Nation of Steel: The Making of Modern America, 1865–1925''. Baltimore: Johns Hopkins University Press, 1995; pgs 32–39)〕 Another difference is that steel can be hardened by heat treating. Historically, wrought iron was known as ''commercially pure iron'';〔.〕〔.〕 however, it no longer qualifies because current standards for commercially pure iron require a carbon content of less than 0.008 wt%.〔.〕〔.〕 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「wrought iron」の詳細全文を読む スポンサード リンク
|